Chlor-alkali Ion Exchange Membrane Market Size, Share, Growth, and Industry Analysis, By Type (Membrane with Sacrificial Thread,Membrane without Sacrificial Thread), By Application (Chlor-Alkali Industry,Water Electrolysis,Electrodialysis,Water Treatment), Regional Insights and Forecast to 2035

Chlor-alkali Ion Exchange Membrane Market Overview

The global Chlor-alkali Ion Exchange Membrane Market is forecast to expand from USD 494.91 million in 2026 to USD 503.82 million in 2027, and is expected to reach USD 581 million by 2035, growing at a CAGR of 1.8% over the forecast period.

The chlor-alkali ion exchange membrane market is a highly specialized sector with global production capacity exceeding 13 million metric tons of caustic soda annually, of which over 80% uses membrane cell technology. Ion exchange membranes offer 95% efficiency in chlorine and caustic soda production, reducing energy use by 20% compared to traditional mercury processes. By 2025, more than 70% of chlor-alkali plants worldwide are projected to transition fully to ion exchange membranes, driven by stricter environmental mandates. Membranes are critical in reducing mercury discharge, aligning with global zero-mercury regulations impacting more than 200 operating plants worldwide.

The United States accounts for nearly 15% of the global chlor-alkali ion exchange membrane demand, with over 4.2 million metric tons of caustic soda produced annually via membrane cell technology. The U.S. maintains more than 45 membrane-based chlor-alkali production facilities, primarily in Louisiana and Texas, supplying key industries such as vinyl chloride monomer production, alumina refining, and pulp and paper processing. The Environmental Protection Agency has mandated the elimination of mercury cells, resulting in 100% transition of U.S. chlor-alkali plants to ion exchange membranes by 2024. Investments exceeding 1.5 million square meters of membrane installations are recorded yearly across U.S. facilities.

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Key Findings

• Key Market Driver: 82% of new chlor-alkali capacity additions globally rely on ion exchange membranes for compliance with zero-mercury guidelines.
• Major Market Restraint: 43% of small-scale producers face high capital costs associated with replacing legacy diaphragm cells with ion exchange membranes.
• Emerging Trends: 61% increase in the adoption of membranes for water electrolysis in green hydrogen projects between 2022 and 2025.
• Regional Leadership: Asia-Pacific contributes 52% of global installed ion exchange membrane capacity, followed by Europe at 28%.
• Competitive Landscape: Top four producers (Asahi Kasei, Chemours, AGC, Dongyue) account for 71% of market share in ion exchange membranes worldwide.
• Market Segmentation: Chlor-alkali industry applications dominate with 67% share, water electrolysis at 18%, electrodialysis at 9%, and water treatment at 6%.
• Recent Development: Between 2023–2025, more than 34 large-scale chlor-alkali plants upgraded with advanced perfluorosulfonic acid membranes, improving efficiency by 15%.

Chlor-alkali Ion Exchange Membrane Market Latest Trends

The market for chlor-alkali ion exchange membranes is witnessing a transformation with widespread adoption in green hydrogen projects. By 2025, over 2.4 GW of electrolysis capacity worldwide is expected to rely on ion exchange membranes, representing a 61% increase since 2022. Chlor-alkali producers in China are scaling operations, installing more than 500,000 square meters of membranes annually to replace outdated diaphragm technology. In Europe, 95% of facilities have already shifted to membranes following the 2021 mercury ban, saving approximately 30 TWh of electricity annually.

Chlor-alkali Ion Exchange Membrane Market Dynamics

DRIVER

"Rising demand for environmentally friendly chlor-alkali processes"

The primary driver of the chlor-alkali ion exchange membrane market is the rising adoption of mercury-free processes. Over 200 mercury-cell-based plants globally have been mandated to shut down or upgrade to membrane cells. This shift has resulted in more than 13 million metric tons of caustic soda now being produced via membranes. Additionally, energy savings of nearly 20% per ton of chlorine produced have encouraged large producers such as those in China and India to scale installations. Membranes are increasingly critical in meeting global sustainability goals, as they reduce greenhouse gas emissions by approximately 6% compared to mercury and diaphragm cell alternatives.

RESTRAINT

"High capital costs for membrane installations"

The major restraint in this market is the high investment required for transitioning from legacy cells to membrane systems. A typical membrane chlor-alkali plant requires between 500 and 600 USD per square meter for installation, leading to capital investments exceeding 200 million USD for large-scale facilities. Small and mid-sized producers, especially in developing regions, struggle with financing. Surveys show that nearly 43% of chlor-alkali producers in Africa and parts of South America delay upgrading due to cost barriers. This creates regional disparities in adoption, as larger players in Asia and Europe dominate production.

OPPORTUNITY

"Growing role in green hydrogen production"

Ion exchange membranes are emerging as a vital component of water electrolysis systems, which are central to green hydrogen production. By 2025, over 18% of installed membranes are expected to serve hydrogen electrolysis applications. Countries such as Japan, Germany, and South Korea have invested in more than 1.8 GW of hydrogen electrolysis capacity utilizing ion exchange membranes. Membranes enable high selectivity of hydrogen and oxygen separation, with efficiency rates exceeding 95%. This represents a major opportunity for suppliers, as the global hydrogen economy is projected to require an additional 5 million square meters of membranes by 2030.

CHALLENGE

"Rising operational costs and durability issues"

Despite advances, operational costs remain a challenge, as membranes require periodic replacement every 7–10 years. Maintenance and replacement expenses account for nearly 15% of total production costs in chlor-alkali plants. Durability challenges arise from exposure to high concentrations of chlorine, which can degrade membrane performance, reducing efficiency from 95% to 87% over time. Companies are investing in enhanced perfluorosulfonic membranes to overcome these issues, but adoption is uneven. Approximately 30% of producers in Southeast Asia report performance degradation within 6 years of installation, highlighting the need for continued innovation.

Chlor-alkali Ion Exchange Membrane Market Segmentation

The chlor-alkali ion exchange membrane market is segmented by type and application, with each contributing unique demand patterns across industries. By type, membranes are classified into those with sacrificial threads and those without. By application, key segments include the chlor-alkali industry, water electrolysis, electrodialysis, and water treatment, with differing adoption levels and performance benchmarks.

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BY TYPE

Membrane with Sacrificial Thread: Membranes with sacrificial threads account for nearly 60% of total installations, with over 700,000 square meters deployed annually worldwide. Their key advantage lies in structural stability under high current density, handling up to 6 kA/m². They are widely used in large chlor-alkali facilities, with China and India being major adopters. More than 50 large plants in Asia employ these membranes for caustic soda production, amounting to 9 million metric tons annually. Their extended lifespan of 8–10 years reduces operational expenses by nearly 10% compared to standard membranes.

Membrane with Sacrificial Thread is projected at USD 282 million in 2025, accounting for 58% of the global market, and anticipated to grow to USD 334 million by 2034 at a CAGR of 1.9%, supported by durability in electrolysis operations.

Top 5 Major Dominant Countries in the Membrane with Sacrificial Thread Segment:

• United States: Valued at USD 72 million in 2025, holding 25.5% share, with a CAGR of 1.9%, supported by over 40 chlor-alkali plants producing 12 million tons of chlorine annually.
• China: Estimated at USD 62 million in 2025, with 22% share, expanding at 2.0% CAGR, driven by high sodium hydroxide output exceeding 36 million tons per year.
• Germany: Worth USD 38 million in 2025, with 13.5% share, CAGR of 1.7%, due to its strong chemical industry producing over 5 million tons of caustic soda yearly.
• Japan: At USD 32 million in 2025, representing 11.3% share, CAGR 1.8%, supported by advanced membrane R&D and chlor-alkali capacity above 4 million tons.
• India: Valued at USD 28 million in 2025, 9.9% share, CAGR of 2.1%, fueled by industrial chlorine demand crossing 3 million tons for PVC and chemicals.

Membrane without Sacrificial Thread: Membranes without sacrificial threads represent 40% of global usage, installed in more than 500,000 square meters annually. These membranes are lighter, easier to install, and deliver energy savings of approximately 12% due to reduced resistance. They dominate applications in medium-scale plants, particularly in Europe, where more than 70% of facilities prefer this type. Their shorter average lifespan of 6–7 years is offset by lower capital investment per square meter, encouraging uptake in cost-sensitive regions such as South America and Africa.

Membrane without Sacrificial Thread is expected at USD 204 million in 2025, accounting for 42% share of the market, projected to reach USD 237 million by 2034 at a CAGR of 1.6%, preferred for reduced maintenance and cost efficiency.

Top 5 Major Dominant Countries in the Membrane without Sacrificial Thread Segment:

• United States: Estimated at USD 56 million in 2025, with 27.5% share and CAGR of 1.7%, driven by modernization of electrolysis facilities with over 20 membrane-based plants.
• China: Worth USD 48 million in 2025, with 23.5% share, expanding at CAGR of 1.8%, as over 60% of new chlor-alkali capacity transitions to non-sacrificial membranes.
• South Korea: Valued at USD 28 million in 2025, 13.7% share, CAGR of 1.5%, reflecting expansion in water electrolysis pilot projects and chemical plants.
• Germany: At USD 26 million in 2025, representing 12.7% share, CAGR of 1.6%, supported by consistent adoption across chlor-alkali facilities replacing older asbestos technology.
• Japan: Estimated at USD 24 million in 2025, 11.7% share, CAGR of 1.6%, driven by sustainable production targets and strong demand in electrodialysis applications.

BY APPLICATION

Chlor-Alkali Industry: The chlor-alkali industry accounts for 67% of membrane usage, covering production of chlorine, caustic soda, and hydrogen. Annual production via membrane cell technology exceeds 13 million metric tons globally. More than 200 plants worldwide use these membranes, with Asia contributing 50% of total demand. Facilities in India alone installed 250,000 square meters of membranes between 2022 and 2025, supplying PVC and alumina industries.

Chlor-Alkali Industry applications are valued at USD 260 million in 2025, accounting for 53.5% share, projected to reach USD 308 million by 2034 at a CAGR of 1.9%, driven by chlorine, caustic soda, and hydrogen output demand.

Top 5 Major Dominant Countries in the Chlor-Alkali Industry Application:

• United States: Estimated at USD 70 million in 2025, 27% share, CAGR 1.8%, supported by over 11 million tons annual caustic soda production across 20 facilities.
• China: Valued at USD 64 million in 2025, with 25% share and CAGR 2.0%, driven by over 36 million tons chlorine production capacity annually.
• India: Worth USD 40 million in 2025, 15.3% share, CAGR 2.1%, fueled by growth in PVC and alumina sectors with demand for 3.5 million tons of caustic soda.
• Germany: At USD 34 million in 2025, 13% share, CAGR 1.7%, reflecting stable consumption across chemical industries with 5 million tons annual chlorine production.
• Japan: Estimated at USD 28 million in 2025, 10.7% share, CAGR 1.8%, supported by advanced technologies and high-performance chemical exports.

Water Electrolysis: Water electrolysis applications represent 18% of global demand, driven by green hydrogen projects. Over 1.8 GW of electrolysis capacity globally is equipped with ion exchange membranes, with Japan and Germany leading installations. Membranes achieve 97% hydrogen purity levels, critical for fuel-cell-grade hydrogen production. Demand is projected to surpass 5 million square meters by 2030, supporting global renewable energy targets.

Water Electrolysis applications stand at USD 85 million in 2025, about 17.5% of the market, projected to grow to USD 98 million by 2034 with CAGR 1.6%, as hydrogen generation gains traction in energy transition initiatives.

Top 5 Major Dominant Countries in the Water Electrolysis Application:

• Japan: Valued at USD 20 million in 2025, 23.5% share, CAGR 1.7%, with over 200 hydrogen fueling stations operational nationwide.
• Germany: Estimated at USD 18 million in 2025, 21% share, CAGR 1.6%, backed by green hydrogen projects producing over 100 MW annually.
• China: Worth USD 16 million in 2025, 18.8% share, CAGR 1.7%, with large-scale hydrogen electrolyzer capacity exceeding 200 MW.
• United States: At USD 15 million in 2025, 17.6% share, CAGR 1.6%, supported by DOE hydrogen hubs projects across multiple states.
• South Korea: Estimated at USD 12 million in 2025, 14.1% share, CAGR 1.5%, driven by government hydrogen roadmaps with more than 10 GW targets by 2030.

Electrodialysis: Electrodialysis applications account for 9% of global membrane demand, with over 120 million cubic meters of brackish water desalinated annually using ion exchange membranes. Adoption is strong in arid regions such as Saudi Arabia and Israel, where over 50 plants integrate electrodialysis technology. Membranes in this segment have shown efficiency improvements of 15% in recent years, reducing desalination costs by 8%.

Electrodialysis applications are valued at USD 72 million in 2025, representing 14.8% share, projected to rise to USD 84 million by 2034 at CAGR of 1.7%, widely used for desalination, wastewater treatment, and ionic separations.

Top 5 Major Dominant Countries in the Electrodialysis Application:

• United States: Valued at USD 20 million in 2025, 27.8% share, CAGR 1.7%, with over 150 desalination plants using electrodialysis systems.
• China: Estimated at USD 18 million in 2025, 25% share, CAGR 1.8%, due to adoption in wastewater recycling and food industry applications.
• India: Worth USD 12 million in 2025, 16.7% share, CAGR 1.8%, with strong uptake in brackish water desalination facilities.
• Germany: At USD 11 million in 2025, 15.3% share, CAGR 1.6%, supported by industrial wastewater purification installations.
• Japan: Estimated at USD 11 million in 2025, 15.2% share, CAGR 1.6%, driven by niche applications in electronics and pharmaceuticals.

Water Treatment: Water treatment contributes 6% of global membrane use, primarily in municipal and industrial wastewater systems. Over 15 million cubic meters of wastewater is treated daily using ion exchange membranes. Adoption in China has risen by 25% since 2022, with more than 80 urban treatment facilities installing membrane modules. These membranes reduce chemical usage by 18%, making them cost-effective for large-scale water purification.

Water Treatment applications are valued at USD 69 million in 2025, comprising 14.2% share, projected to reach USD 81 million by 2034 at CAGR 1.6%, supported by rising clean water demand and municipal infrastructure projects.

Top 5 Major Dominant Countries in the Water Treatment Application:

• United States: Valued at USD 18 million in 2025, 26% share, CAGR 1.7%, with over 16,000 municipal treatment facilities operational.
• China: Estimated at USD 16 million in 2025, 23% share, CAGR 1.7%, supported by 500+ large-scale treatment plants nationwide.
• India: Worth USD 13 million in 2025, 19% share, CAGR 1.8%, backed by government water missions targeting 100 million households.
• Germany: At USD 12 million in 2025, 17.3% share, CAGR 1.6%, reflecting modernization of over 5,000 wastewater treatment plants.
• Brazil: Estimated at USD 10 million in 2025, 14.7% share, CAGR 1.7%, driven by urbanization and need for safe potable water infrastructure.

Chlor-alkali Ion Exchange Membrane Market Regional Outlook

Asia-Pacific dominates with 52% of global installations producing over 9 million metric tons annually, led by China’s 6 million metric tons and India’s 1.2 million metric tons. Europe holds 28% share with more than 6 million metric tons capacity, supported by Germany’s 1.5 million metric tons. North America accounts for 20% output at 4.2 million metric tons, while the Middle East & Africa contributes 7% with 1.2 million metric tons capacity led by Saudi Arabia at 500,000 metric tons.

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NORTH AMERICA

North America accounts for nearly 20% of global membrane demand, with more than 4.2 million metric tons of caustic soda produced annually using ion exchange membranes. The U.S. leads with 45 operational membrane plants, contributing 85% of regional production. Canada has installed over 120,000 square meters of membranes in pulp and paper industries. Mexico’s chlor-alkali output of 800,000 metric tons annually is fully based on membrane technology, with strong links to PVC manufacturing. Growth is supported by strict EPA regulations eliminating mercury cells, making North America a fully converted membrane market.

North America is valued at USD 130 million in 2025, holding 26.7% share of the global market, with CAGR 1.7%, supported by chemical industries and over 25 active chlor-alkali plants across the region.

North America - Major Dominant Countries in the “Chlor-alkali Ion Exchange Membrane Market”

• United States: USD 95 million in 2025, 73% regional share, CAGR 1.8%, backed by world’s second-largest chlorine production exceeding 12 million tons.
• Canada: USD 18 million in 2025, 14% share, CAGR 1.6%, supported by pulp and paper industry demand.
• Mexico: USD 12 million in 2025, 9.2% share, CAGR 1.7%, driven by growing PVC demand.
• Trinidad & Tobago: USD 3 million in 2025, 2.3% share, CAGR 1.5%, supporting small-scale chemical exports.
• Guatemala: USD 2 million in 2025, 1.5% share, CAGR 1.5%, used in limited water treatment projects.

EUROPE

Europe represents 28% of global demand, with over 6 million metric tons of chlor-alkali output produced annually using ion exchange membranes. Germany leads with 1.5 million metric tons capacity, followed by France and Italy with 800,000 and 700,000 metric tons respectively. More than 95% of chlor-alkali facilities in Europe transitioned to membranes by 2023, in compliance with EU mercury ban directives. Europe also records strong demand in green hydrogen, with 1.2 GW of electrolysis projects operational using ion exchange membranes, particularly in Germany and the Netherlands.

Europe is valued at USD 135 million in 2025, making up 27.7% share, with CAGR of 1.7%, led by Germany, France, Italy, and the UK with strong chlor-alkali industries producing over 8 million tons chlorine annually.

Europe - Major Dominant Countries in the “Chlor-alkali Ion Exchange Membrane Market”

• Germany: USD 48 million in 2025, 35.5% share, CAGR 1.7%, largest chlorine producer in EU.
• France: USD 28 million in 2025, 20.7% share, CAGR 1.6%, with strong PVC industry.
• Italy: USD 22 million in 2025, 16.2% share, CAGR 1.6%, focused on caustic soda for alumina refining.
• United Kingdom: USD 20 million in 2025, 14.8% share, CAGR 1.6%, supported by chlorinated solvent demand.
• Spain: USD 17 million in 2025, 12.5% share, CAGR 1.5%, driven by water treatment industries.

ASIA-PACIFIC

Asia-Pacific dominates with 52% of total global installations, representing more than 9 million metric tons of chlor-alkali output via membranes annually. China alone accounts for 6 million metric tons, supported by installations of more than 500,000 square meters of membranes per year. India follows with 1.2 million metric tons of production capacity fully dependent on membranes. Japan and South Korea are leading in hydrogen electrolysis adoption, with 500 MW of membrane-based hydrogen projects. Rapid industrialization, PVC expansion, and desalination projects make Asia-Pacific the fastest-growing regional market.

Asia is projected at USD 165 million in 2025, accounting for 34% share of the market, CAGR of 1.9%, led by China, India, and Japan with combined chlorine production exceeding 45 million tons annually.

Asia - Major Dominant Countries in the “Chlor-alkali Ion Exchange Membrane Market”

• China: USD 85 million in 2025, 52% regional share, CAGR 2.0%, world’s largest chlorine producer.
• India: USD 38 million in 2025, 23% share, CAGR 2.1%, driven by PVC and alumina demand.
• Japan: USD 25 million in 2025, 15% share, CAGR 1.8%, advanced in hydrogen electrolysis.
• South Korea: USD 10 million in 2025, 6.2% share, CAGR 1.6%, water electrolysis pilot projects.
• Indonesia: USD 7 million in 2025, 4.8% share, CAGR 1.6%, expanding in water treatment and chemicals.

MIDDLE EAST & AFRICA

The Middle East & Africa accounts for 7% of global demand, with 1.2 million metric tons of chlor-alkali production capacity utilizing membranes. Saudi Arabia leads with 500,000 metric tons of output for PVC and water desalination. South Africa produces over 200,000 metric tons annually, primarily for mining applications. Israel operates advanced electrodialysis projects treating 100 million cubic meters of water annually. Rising investments in desalination plants, projected to reach 300 facilities by 2030, will significantly expand membrane adoption in the region.

Middle East and Africa is valued at USD 56 million in 2025, holding 11.6% share, CAGR 1.6%, led by Saudi Arabia, UAE, South Africa, and Egypt with over 6 million tons of annual chlor-alkali capacity.

Middle East and Africa - Major Dominant Countries in the “Chlor-alkali Ion Exchange Membrane Market”

• Saudi Arabia: USD 20 million in 2025, 35.7% share, CAGR 1.6%, driven by large chlor-alkali plants linked to petrochemicals.
• United Arab Emirates: USD 10 million in 2025, 17.9% share, CAGR 1.7%, with desalination and chlor-alkali integration.
• South Africa: USD 9 million in 2025, 16% share, CAGR 1.6%, supporting mining and chemicals.
• Egypt: USD 9 million in 2025, 16% share, CAGR 1.7%, chlorine used in plastics and fertilizers.
• Nigeria: USD 8 million in 2025, 14.4% share, CAGR 1.6%, adoption in water treatment sector.

List of Top Chlor-alkali Ion Exchange Membrane Companies

• Chemours
• Asahi Kasei
• Dongyue Group
• AGC

Top Companies by Market Share:

• Asahi Kasei: Holds 28% global market share, with more than 3 million square meters of membranes installed annually.
• AGC: Accounts for 22% market share, supplying over 2.5 million square meters of membranes each year across 40 countries.

Investment Analysis and Opportunities

Investments in the chlor-alkali ion exchange membrane market are rising significantly, with over 1.5 billion USD allocated annually towards membrane upgrades and expansions. China invested in more than 500,000 square meters of new installations between 2023 and 2025 to support 6 million metric tons of caustic soda production. In Europe, 1.2 GW of hydrogen electrolysis capacity adopted ion exchange membranes in 2024, accounting for 25% of regional green hydrogen projects. North America invested in over 200,000 square meters of membranes annually for pulp, paper, and alumina refining applications. Opportunities lie in water desalination, projected to treat 15 million cubic meters daily by 2027, and in green hydrogen, where membrane demand will exceed 5 million square meters by 2030.

New Product Development

Innovation in ion exchange membranes has accelerated between 2023 and 2025, with companies developing higher durability and chlorine-resistant membranes. AGC introduced a new perfluorosulfonic acid membrane capable of operating at 6 kA/m², improving efficiency by 12%. Asahi Kasei developed membranes with 97% selectivity, reducing caustic soda contamination by 20%. Chemours launched lightweight membranes reducing installation time by 30% while improving energy efficiency by 10%. Dongyue Group scaled up manufacturing to 1 million square meters annually, focusing on hydrogen electrolysis membranes for green energy projects. These innovations extend membrane lifespans to 10 years, cutting replacement costs by 15% for operators.

Five Recent Developments

• In 2023, Asahi Kasei installed 250,000 square meters of membranes in India, supporting 1.2 million metric tons of caustic soda production.
• In 2024, AGC launched its latest chlorine-resistant membrane, adopted in 12 large chlor-alkali plants across Europe.
• In 2024, Dongyue Group expanded capacity to 1 million square meters annually, supplying China’s 6 million metric tons chlor-alkali industry.
• In 2025, Chemours introduced lightweight membranes, reducing installation costs by 18% across U.S. chlor-alkali plants.
• In 2025, Japan commissioned 300 MW of hydrogen electrolysis capacity using Asahi Kasei membranes for green hydrogen production.

Report Coverage

The Chlor-alkali Ion Exchange Membrane Market Report covers detailed market segmentation by type, application, and region. It includes analysis of membranes with sacrificial thread and without sacrificial thread, accounting for 60% and 40% of market share respectively. Application coverage extends across the chlor-alkali industry (67% share), water electrolysis (18%), electrodialysis (9%), and water treatment (6%). Regional analysis highlights Asia-Pacific (52% share), Europe (28%), North America (20%), and Middle East & Africa (7%). The report also profiles leading companies including Asahi Kasei, AGC, Chemours, and Dongyue Group, which collectively hold over 70% of global share. Additionally, the report provides investment analysis, recent innovations, and five major developments between 2023 and 2025, offering comprehensive insights for B2B buyers, manufacturers, and investors seeking opportunities in this market.

Chlor-alkali Ion Exchange Membrane Market Report Coverage

REPORT COVERAGE	DETAILS
Market Size Value In	USD 494.91 Million in 2026
Market Size Value By	USD 581 Million by 2035
Growth Rate	CAGR of 1.8% from 2026-2035
Forecast Period	2026 - 2035
Base Year	2025
Historical Data Available	Yes
Regional Scope	Global
Segments Covered	By Type : Membrane with Sacrificial Thread Membrane without Sacrificial Thread By Application : Chlor-Alkali Industry Water Electrolysis Electrodialysis Water Treatment
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